Analysis of the Influence of Temperature and Gas Humidity on the \ud Performance Stability of Polymer Electrolyte Membrane Fuel Cells

摘要

Adequate water management represents one of the main challenges in the design and operation of polymer electrolyte membrane\udfuel cells. In this work, the influence of inlet gas humidification on cell performance is investigated by in-situ current density\udmeasurements obtained using the segmented cell approach. Particular attention is paid to the combined effect of cell temperature\udand relative humidity of the anode and cathode feed streams. When operated at 80◦C and low humidity conditions, the cell is seen\udto undergo a severe voltage decline that is not observed at 60◦C. The analysis shows that the variation with temperature of the water\uduptake rate of the gaseous streams plays a key role in determining the observed differences in performance stability. In the case of\ud60◦C operation, the water uptake rate of the cathode stream at 50% inlet relative humidity is roughly 30% of its value at 80◦C at the\udsame humidification level, resulting in a significantly lower drying capacity. A simple balance of water model, able to explain the\udobserved cell behavior, is finally presented and discussed.